Search results for "METAL OXIDE"

Tailoring oxide properties: An impact on adsorption characteristics of molecules and metals

2014

Abstract Both density functional theory calculations and numerous experimental studies demonstrate a variety of unique features in metal supported oxide films and transition metal doped simple oxides, which are markedly different from their unmodified counterparts. This review highlights, from the computational perspective, recent literature on the properties of the above mentioned surfaces and how they adsorb and activate different species, support metal aggregates, and even catalyse reactions. The adsorption of Au atoms and clusters on metal-supported MgO films are reviewed together with the cluster׳s theoretically predicted ability to activate and dissociate O 2 at the Au–MgO(100)/Ag(100…

Mo-W-containing tetragonal tungsten bronzes through isomorphic substitution of molybdenum by tungsten

2010

Mixed metal oxides based in Mo(W)–Nb–V–Te with tetragonal tungsten bronze (TTB) structure have been synthesized by a hydrothermal method from aqueous solutions of the corresponding Keggin-type heteropolyacids and further heat-treatment in N2 at 700 ◦ C. The materials have been characterized by several physico-chemical techniques, i.e. XRD, Raman, FTIR, SEM-EDS, and TEM. This procedure allows controlling the chemical species to be distributed in the different interstices of the TTB skeleton, which is a key factor to regulate the catalytic properties of the final solid. In this sense, the isomorphic replacement of Mo by W results in lattice parameter and crystal morphology variation, although…

Production of ethyl lactate by activated carbon-supported Sn and Zn oxide catalysts utilizing lignocellulosic side streams

2021

In this study, activated carbon-supported Sn and Zn oxide catalysts were prepared from hydrolysis lignin and used for the conversion of model solutions of trioses, hexoses, and lignocellulosic biomass hydrolysates to ethyl lactate. Both catalysts, SnO2@AC and ZnO@AC, were able to produce ethyl lactate in high yields. SnO2@AC was a more active and selective catalyst in triose (dihydroxyacetone) conversion, providing 99% yield to ethyl lactate. ZnO@AC, by contrast, was more selective in glucose and hydrolysate conversion, with a yield of 60% and 85%, respectively. The ethyl lactate yields were significantly higher than those from the optimized model solution experiments when using ZnO@AC cata…

FRUIT QUALITY EVALUATION OF FOUR LOQUAT CULTIVARS GROWN IN SICILY

2011

Chemical (soluble solids content, titratable acidity, pH), morphological (weight, longitudinal and transversal diameter, thickness of the flesh, number of seeds, peel colour), and sensorial characteristics of four loquat cultivars (‘Algerie’, ‘Claudia’, ‘Nespolone di Trabia’ and ‘Sanfilippara’) from mature, organically-grown trees in Sicily, were analysed. The determinations were carried out by traditional instrumental techniques, by a panel test and by an electronic olfactory system. A panel of 10 trained judges was used to determine intensity of some attributes in the sensory profile of the different cultivars, while the electronic olfactory system was used to identify possible difference…

Nanostructures of Lanthanide Oxy/Hydroxides Obtained by Metal Displacement Deposition

2012

Characterization of defect density states in MoOx for c-Si solar cell applications

Layers of MoOx have been deposited by thermal evaporation followed by post-deposition annealing (PDA). The density of states (DOS) distributions of the MoOx films were extracted deconvoluting the absorption spectra, measured by a phothermal deflection spectroscopy setup, including the small polaron contribution. Results revealed a sub-band defect distribution centered 1.1 eV below the conduction band; the amplitude of this distribution was found to increase with PDA temperature and film thickness.

Efficiency comparison between SiC- and Si-based active neutral-point clamped converters

2015

This paper presents an efficiency comparison between silicon-carbide technology and silicon technology. In order to achieve this, the efficiency of an active neutral-point clamped converter built up with silicon carbide power-devices is compared with the efficiency of an active neutral-point clamped converter built up with silicon power-devices, under a particular operating mode and a particular selection of devices. Firstly, overall losses of both converters are estimated. Then, experimental tests are carried out to measure their overall losses and efficiency. Finally, experimental results are compared with the estimations to support the analysis. The efficiency of the SiC converter is hig…

Nanostructures of different oxides/hydroxides grown in nanoporous templates by electrochemical methods.

2011

Electrochemical oxidation of organic pollutants in water at metal oxide electrodes: A simple theoretical model including direct and indirect oxidatio…

2009

Abstract The electrochemical oxidation of organics in water at metal oxide electrodes was investigated with the aim to discuss the correlations between the instantaneous current efficiency ICE and operative conditions by considering both the hypothesis of a direct oxidation process and of an indirect process mediated by adsorbed hydroxyl radicals or chemisorbed “oxygen”, in order to explicit the main differences expected between these cases. Thus, a simple theoretical model was discussed, as an extension of previous studies of Comnnellis and co-workers which were focused on indirect oxidation paths [C. Comninellis, Electrochim. Acta 39 (1994) 1857; O. Simond, V. Schaller, Ch. Comninellis, E…

Hybrid organic-inorganic Light Emitting Diodes

2013

Hybrid organic inorganic light emitting diodes are nowadays attracting great attention due to their intrinsic air stability and solution processability, which could result in low-cost, large area, light emitting devices. Despite the fact that high luminance values have been already demonstrated in recent publications, the efficiency of HyLEDs has been limited by its peculiar hole-dominated electronic mechanism. In particular, the electron injection is promoted by the hole accumulation at the metal oxide EIL/organic interface, but at the same time this mechanism leads to limits the device efficiency. It is known from the research in OLEDs that when the recombination zone is close to an inter…